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Download PDF MARCH’S ADVANCED ORGANIC CHEMISTRY REACTIONS, MECHANISMS, AND STRUCTURE SEVENTH EDITION by Michael B. Smith


Sinopsis

Localized chemical bonding may be defined as bonding in which the electrons are sharedby two and only two nuclei. Such bonding is the essential feature associated with the structure of organic molecules.1 Chapter 2 will discuss delocalized bonding, in which electrons are shared by more than two nuclei.



Content

  1. Localized Chemical Bonding
  2. Delocalized Chemical Bonding
  3. Bonding Weaker Than Covalent
  4. Stereochemistry and Conformation
  5. Carbocations, Carbanions, Free Radicals, Carbenes, and Nitrenes
  6. Mechanisms and Methods of Determining them
  7. Irradiation Processes in Organic Chemistry
  8. Acids and Bases
  9. Effects of Structure and Medium on Reactivity
  10. Aliphatic Substitution, Nucleophilic and Organometallic
  11. Aromatic Substitution, Electrophilic
  12. Aliphatic, Alkenyl, and Alkynyl Substitution, Electrophilic and Organometallic
  13. Aromatic Substitution: Nucleophilic and Organometallic
  14. Substitution Reactions: Radical
  15. Addition to Carbon–Carbon Multiple Bonds
  16. Addition to Carbon–Hetero Multiple Bonds
  17. Eliminations
  18. Rearrangements
  19. Oxidations and Reductions



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